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Coextraction of vanadium and manganese from high-manganese containing vanadium wastewater by a solvent

Zishuai Liu, Yimin Zhang, Zilin Dai, Jing Huang, Cong Liu

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 902-912 doi: 10.1007/s11705-019-1887-z

摘要： High-manganese containing vanadium wastewater (HMVW) is commonly produced during the vanadium extraction process from vanadium titano-magnetite. HMVW cannot be reused and discharged directly, and is harmful to the environment and affect product quality due to heavy metals in the wastewater. The wastewater is usually treated by lime neutralization, but valuable metals (especially V and Mn) cannot be recovered. In this study, an efficient and environmentally friendly method was developed to recover valuable metals by using a solvent extraction-precipitation process. In the solvent extraction process, 98.15% of vanadium was recovered, and the V O product, with a purity of 98.60%, was obtained under optimal conditions. For the precipitation process, 91.05% of manganese was recovered as MnCO which meets the III grade standard of HG/T 2836-2011. Thermodynamic simulation analysis indicated that MnCO was selectively precipitated at pH 6.5 while Mg and Ca could hardly be precipitated. The results of X-ray diffraction and scanning electron microscopy demonstrated that the obtained V O and MnCO displayed a good degree of crystallinity. The treated wastewater can be returned for leaching, and resources (V and Mn) in the wastewater were utilized efficiently in an environmentally friendly way. Therefore, this study provides a novel method for the coextraction of V and Mn from HMVW.

关键词： high-manganese containing vanadium wastewater     solvent extraction     carbonate precipitation     vanadium titano-magnetite     valuable metal recovery    

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Simultaneous enhanced ammonia and nitrate removal from secondary effluent in constructed wetlands using a new manganese-containing

《环境科学与工程前沿（英文）》 2023年 第18卷 第4期 doi: 10.1007/s11783-024-1807-4

摘要：

● MnO2/PCL composite material (MPCM) enhances ammonia and nitrate removal in CWs.

关键词： Constructed wetland     Nitrogen removal     Manganese redox     Polycaprolactone     Nitrous oxide    

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Construction of defect-containing UiO-66/MoSe heterojunctions with superior photocatalytic performancefor wastewater treatment and mechanism insight

《化学科学与工程前沿（英文）》 2023年 第17卷 第4期   页码 449-459 doi: 10.1007/s11705-022-2226-3

摘要： Metal–organic frameworks are recognized as promising multifunctional materials, especially metal–organic framework-based photocatalysts, which are considered to be ideal photocatalytic materials. Herein, a new type of UiO-66/MoSe2 composite was prepared using the solvothermal method. The optimum composite was selected by adjusting the mass ratio of UiO-66 and MoSe2. X-ray diffraction analysis showed that the mass ratio influenced the crystal plane exposure rate of the composite, which may have affected its photocatalytic performance. The composite is composed of ultra-thin flower-like MoSe2 that wrapped around cubic UiO-66, a structure that increases the abundance of active sites for reactions and is more conducive to the separation of carriers. The photocatalytic properties of the composite were evaluated by measuring the degradation rate of Rhodamine B and the catalyst’s ability to reduce Cr(VI)-containing wastewater under visible light irradiation. Rhodamine B was decolorized completely in 120 min, and most of the Cr(VI) was reduced within 150 min. The photochemical mechanism of the complex was studied in detail. The existence of Mo6+ and oxygen vacancies, in addition to the Z-type heterojunction promote the separation of electrons and holes, which enhances the photocatalytic effect.

关键词： UiO-66/MoSe2     photocatalysis     dye-containing wastewater     heavy metal wastewater     oxygen vacancies    

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Stability analysis of alkaline nitrobenzene-containing wastewater by a catalyzed Fe-Cu treatment process

FAN Jinhong, XU Wenying, GAO Tingyao, MA Luming

《环境科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 504-508 doi: 10.1007/s11783-007-0081-6

摘要： Iron and copper bimetallic system (catalyzed Fe-Cu process) is a promising technology for alkaline nitrobenzene-containing wastewater treatment. However, little is currently known about the changes of treatment efficiency with time

关键词： technology     bimetallic     catalyzed     nitrobenzene-containing wastewater     efficiency    

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Submerged arc plasma system combined with ozone oxidation for the treatment of wastewater containing

《环境科学与工程前沿（英文）》 2021年 第15卷 第5期 doi: 10.1007/s11783-020-1384-0

摘要：

• Submerged arc plasma was introduced in terms of wastewater treatment.

关键词： Thermal plasma     Submerged arc plasma     Wastewater     Ozone     Phenol     Highly energetic electron    

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Multivalent manganese oxides with high electrocatalytic activity for oxygen reduction reaction

Xiangfeng Peng, Zhenhai Wang, Zhao Wang, Yunxiang Pan

《化学科学与工程前沿（英文）》 2018年 第12卷 第4期   页码 790-797 doi: 10.1007/s11705-018-1706-y

摘要： A noble-metal-free catalyst based on both Mn O and MnO was prepared by using the dielectric barrier discharge technique at moderate temperature. The prepared catalyst shows a higher electrocatalytic activity towards the oxygen reduction reaction than the catalyst prepared by using the traditional calcination process. The enhanced activity could be due to the coexistence of manganese ions with different valences, the higher oxygen adsorption capacity, and the suppressed aggregation of the catalyst nanoparticles at moderate temperature. The present work would open a new way to prepare low-cost and noble-metal-free catalysts at moderate temperature for more efficient electrocatalysis.

关键词： oxygen reduction reaction     manganese oxides     mixed valences of manganese     oxygen adsorption     dielectric barrier discharge    

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Vanadium(IV) solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 56-67 doi: 10.1007/s11705-022-2185-8

摘要： Separation of vanadium from black shale leaching solution at low pH is very meaningful, which can effectively avoid the generation of alkali neutralization slag and the resulting vanadium loss. In this study, coordination mechanism of vanadium in acid leaching solution at low pH was investigated with the intervention of chloride ions. Under the conditions of pH 0.8, di-(2-ethylhexyl)phosphoric acid concentration of 20%, phase ratio of 1:2, and extraction time of 8 min, the vanadium extraction could reach 80.00%. The Fourier transform infrared and electrospray ionization results reveal that, despite the fact that the chloride ion in the leachate could significantly promote vanadium extraction, the chloride ion does not enter the organic phase, indicating an intriguing phenomenon. Among Cl−–V, SO42−–V, and H2O–V, the V–Cl bond is longer and the potential difference between coordinate ions and vanadium is smaller. Therefore, VO2+ gets easily desorbed with chloride ions and enter the organic phase. At the same time, the hydrogen ions of di-(2-ethylhexyl)phosphoric acid also enter the water phase more easily, which reduces the pH required for the extraction reaction.

关键词： vanadium     black shale     solvent extraction     high acidity extraction    

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Broadening of appropriate demulsifier dosage range for latex-containing wastewater by sulfate addition

Shengzhi Zheng, Yudong Song, Yiming Li, Lidong Sun, Bin Hu, Mingdong An, Yuexi Zhou

《环境科学与工程前沿（英文）》 2018年 第12卷 第6期 doi: 10.1007/s11783-018-1041-z

摘要：

The effect of latex concentration on appropriate demulsifier dosage was investigated.

The appropriate demulsifier dosage range was controlled by zeta potential.

Sulfate could broaden appropriate demulsifier dosage range and improve latex removal.

关键词： Demulsification     Polybutadiene latex wastewater     Polyaluminum chloride     Zeta potential     Sulfate addition    

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Enhanced biohydrogen generation from organic wastewater containing N H 4 + by phototrophic bacteria Rhodobacter

Guanghong ZHENG, Zhuhui KANG, Yifan QIAN, Lei WANG,

《环境科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 387-392 doi: 10.1007/s11783-009-0154-9

摘要： Haifa RAJHI,Daniel PUYOL,Mirna C. MARTÍNEZ,Emiliano E. DÍAZ,José L. SANZ. [J]. Front. Environ. Sci. Eng., 2016, 10(3): 513-521.Yongtao LV,Xuan CHEN,Lei WANG,Kai JU,Xiaoqiang CHEN,Rui MIAO,Xudong WANG. [J]. Front. Environ. Sci. Eng., 2016, 10(2): 390-398.Zulkifly JEMAAT,Josep Anton TORA,Albert BARTROLI,Julián CARRERA,Julio PEREZ. [J]. Front. Environ. Sci. Eng., 2015, 9(3): 528-533.Wei LI, Xiaowen DING, Min LIU, Yuewen GUO, Lei LIU. [J]. Front Envir Sci Eng, 2012, 6(6): 892-900.Guochen ZHENG, Jianzheng LI, Feng ZHAO, Liguo ZHANG, Li WEI, Qiaoying BAN, Yongsheng ZHAO. [J]. Front Envir Sci Eng, 2012, 6(1): 125-130.Hailong LIN, Weiguang LI, Changhong GUO, Sihang QU, Nanqi REN. [J]. Front Envir Sci Eng Chin, 2011, 5(4): 519-525.Daijun ZHANG, Cui BAI, Ting TANG, Qing YANG. [J]. Front Envir Sci Eng Chin, 2011, 5(2): 291-297.Yanhui ZHAN, Jianwei LIN, Yanling QIU, Naiyun GAO, Zhiliang ZHU. [J]. Front Envir Sci Eng Chin, 2011, 5(1): 65-75.Rongchang WANG, Xinmin ZHAN, Yalei ZHANG, Jianfu ZHAO. [J]. Front Envir Sci Eng Chin, 2011, 5(1): 48-56.Bo WANG, Wei WAN, Jianlong WANG, . [J]. Front.Environ.Sci.Eng., 2009, 3(4): 380-386.GUO Jinsong, YANG Guohong, FANG Fang, QIN Yu. [J]. Front.Environ.Sci.Eng., 2008, 2(4): 439-445.GENG Bing, ZHU Yanfang, JIN Zhaohui, LI Tielong, KANG Haiyan, WANG Shuaima. [J]. Front.Environ.Sci.Eng., 2007, 1(3): 357-361.WU Deyi, HU Zhanbo, WANG Xinze, HE Shengbing, KONG Hainan. [J]. Front.Environ.Sci.Eng., 2007, 1(2): 213-220.XU Zhengyong, YANG Zhaohui, ZENG Guangming, XIAO Yong, DENG Jiuhua. [J]. Front.Environ.Sci.Eng., 2007, 1(1): 43-48.

关键词： ammonium     anoxygenic phototrophic bacterium     biohydrogen     glutamine auxotrophic     tofu wastewater    

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Anaerobic treatment of wastewater containing methanol in up-flow anaerobic sludge bed (UASB) reactor

LIN Yishan, HE Yanling, MENG Zhuo, YANG Shucheng

《环境科学与工程前沿（英文）》 2008年 第2卷 第2期   页码 241-246 doi: 10.1007/s11783-008-0040-x

摘要： The direct conversion of methanol into methane is the main process in anaerobic treatment of methanol containing wastewater. However, acetic acid can also be produced from methanol theoretically, which may probably result in an abrupt pH drop and deteriorate the anaerobic process. Therefore, it is interesting to know what would really happen in an anaerobic reactor treating methanol wastewater. In this study, an up-flow anaerobic sludge bed (UASB) reactor treating methanol wastewater was operated. The chemical oxygen demand (COD), acetic acid and pH of the effluent were monitored at different loadings and influent alkalinity. The results showed that the anaerobic reactor could be operated steadily at as low as 119 mg/L of influent alkalinity and high organic loading rate with no obvious pH drops. Volatile fatty acids accumulation was not observed even at strong shock loadings. The microorganisms in the sludge at the end of the test became homogeneous in morphology, which were mainly spherical or spheroidal in shape.

关键词： homogeneous     spherical     influent alkalinity     process     anaerobic treatment    

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Dendritic BiVO4 decorated with MnOx co-catalyst as an efficient hierarchical catalyst for photocatalytic ozonation

Jin Yang, Xuelian Liu, Hongbin Cao, Yanchun Shi, Yongbing Xie, Jiadong Xiao

《化学科学与工程前沿（英文）》 2019年 第13卷 第1期   页码 185-191 doi: 10.1007/s11705-018-1713-z

摘要： An appropriate co-catalyst can significantly promote the photocatalytic efficacy, but this has been seldom studied in the visible-light photocatalysis combined with ozone, namely photocatalytic ozonation. In this work, a dendritic bismuth vanadium tetraoxide (BiVO ) material composited with highly dispersed MnO nanoparticles was synthesized, and its catalytic activity is 86.6% higher than bare BiVO in a visible light and ozone combined process. Catalytic ozonation experiments, ultra-violet-visible (UV-Vis) diffuse reflectance spectra and photoluminescence spectra jointly indicate that MnO plays a triple role in this process. MnO strengthens the light adsorption and promotes the charge separation on the composite material, and it also shows good activity in catalytic ozonation. The key reactive species in this process is ·OH, and various pathways for its generation in this process is proposed. This work provides a new direction of catalyst preparation and pushes forward the application of photocatalytic ozonation in water treatment.

关键词： manganese oxide     bismuth vanadium tetraoxide     photocatalytic ozonation     hydroxyl radical     co-catalyst    

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A review on anammox process for the treatment of antibiotic-containing wastewater: Linking effects with

Jinjin Fu, Quan Zhang, Baocheng Huang, Niansi Fan, Rencun Jin

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1309-y

摘要： Abstract • Anammox is promising for nitrogen removal from antibiotic-containing wastewater. • Most antibiotics could inhibit the anammox performance and activity. • Antibiotic pressure promoted the increase in antibiotic resistance genes (ARGs). • Antibiotic-resistance mechanisms of anammox bacteria are speculated. Antibiotic is widely present in the effluent from livestock husbandry and the pharmaceutical industry. Antibiotics in wastewater usually have high biological toxicity and even promote the occurrence and transmission of antibiotic resistant bacteria and antibiotic resistance genes. Moreover, most antibiotic-containing wastewater contains high concentration of ammonia nitrogen. Improper treatment will lead to high risk to the surrounding environment and even human health. The anaerobic ammonium oxidation (anammox) with great economic benefit and good treatment effect is a promising process to remove nitrogen from antibiotic-containing wastewater. However, antibiotic inhibition has been observed in anammox applications. Therefore, a comprehensive overview of the single and combined effects of various antibiotics on the anammox system is conducted in this review with a focus on nitrogen removal performance, sludge properties, microbial community, antibiotic resistance genes and anammox-involved functional genes. Additionally, the influencing mechanism of antibiotics on anammox consortia is summarized. Remaining problems and future research needs are also proposed based on the presented summary. This review provides a better understanding of the influences of antibiotics on anammox and offers a direction to remove nitrogen from antibiotic-containing wastewater by the anammox process.

关键词： Anammox     Antibiotic     Mechanism     Inhibition    

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Linear viscoelastic behavior of asphalt binders and mixtures containing very high percentages of reclaimed

《结构与土木工程前沿（英文）》   页码 1211-1227 doi: 10.1007/s11709-023-0983-9

摘要： The primary aim of this study is to correlate the impact of aggregates, if any, on the viscoelastic behavior of rejuvenated asphalt mixtures containing very high amounts of reclaimed asphalt pavement (RAP) (> 50%). First, gradation of 100% RAP was rectified, using a modified Bailey method by adding virgin aggregates to achieve two coarse dense-graded and one fine dense-graded blends. Complex modulus test was then performed from −35 to +35 °C and 0.01–10 Hz. In addition to performance grade (PG) testing, extracted and recovered binders from different asphalt mixtures underwent shear complex modulus test within −8 °C to high temperature PG and frequencies from 0.001 to 30 Hz. Cole−Cole, Black space, complex modulus and phase angle master curves were constructed and Shift-Homothety-Shift in time-Shift (SHStS) transformation was used to compare the linear viscoelastic behavior of asphalt binders and mixtures. The influence of aggregates on the viscoelastic behavior of asphalt mixtures depends on temperature and/or frequency. The role of asphalt binders in the behavior of asphalt mixtures is more pronounced at high temperatures and the effect of the aggregate structure increases as the temperature falls. The maximum difference (60% to 70%) in the viscoelastic behavior of the binder and mixture based on SHStS transformed Cole−Cole curves is within the phase angle of 15°–20°.

关键词： RAP     complex modulus     SHStS transformation     rejuvenation     behavior of asphalt binder and mixture    

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Lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 755-763 doi: 10.1007/s11705-022-2137-3

摘要： As draw solute is the core element of forward osmosis (FO) technology, here Li-Bet-Tf2N synthesized from a customized ionic liquid betainium bis(trifluoromethylsulfonyl)imide ([Hbet][Tf2N]) and Li2CO3 recovered from lithium-ion battery (LIB) wastes is proposed as a novel draw solute to treat Li+-containing wastewater from LIB manufacturing through FO filtration. Having high dissociation ability and an extended structure, Li-Bet-Tf2N generates a sufficiently high osmotic pressure to drive the FO filtration efficiently along with insignificant reverse solute diffusion. Li-Bet-Tf2N produces a water flux of 21.3 L·(m2·h)−1 at 1.0 mol∙L–1 against deionized water, surpassing conventional NaCl and MgCl2 draw solutes with a higher water recovery efficiency and a smaller solute loss. Li-Bet-Tf2N induces a more stable and higher water permeation flux with a 10.0% water flux decline than NaCl and MgCl2 for which the water fluxes decline 16.7% and 16.4%, respectively, during the treatment of 2000 mg∙L–1 Li+-containing wastewater for 12 h. More remarkably, unlike other draw solutes which require intensive energy input and complicated processes in recycling, Li-Bet-Tf2N is easily separated from water via solvent extraction. Reproducible results are achieved with the recycled Li-Bet-Tf2N. Li-Bet-Tf2N thus demonstrates a novel class of draw solute with great potentials to treat wastewater economically.

关键词： forward osmosis     lithium-ion battery     draw solution     lithium-containing wastewater     water treatment    

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高压高产含硫气井测试技术及应用

王世泽,唐瑞江, 赵祚培,杜林

《中国工程科学》 2010年 第12卷 第10期   页码 56-60

摘要：

川东北海相气藏埋藏深、温度压力高、普遍含硫、平面及纵向产量变化大，测试工艺复杂，面临井下工具受限、井下事故复杂、井控及环境污染风险大等难题。在川东北高含硫气井测试实践与经验基础上，形成了高压高产含硫气井测试技术。形成了三类六套APR射孔—酸压—测试联作短期测试管柱；管柱力学分析、多级压力控制、国产抗硫及复合地面流程等测试配套工艺满足各类测试要求；以压井、防喷、防漏为主的测试应急方案及措施确保了作业安全。该技术在YB1-侧1，YB12，HB1-1D等井中成功应用，为该类气田勘探开发的顺利进行提供了技术支撑。

关键词： 高压高产     含硫     气藏     测试    

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标题 作者 时间 类型 操作

Coextraction of vanadium and manganese from high-manganese containing vanadium wastewater by a solvent

Zishuai Liu, Yimin Zhang, Zilin Dai, Jing Huang, Cong Liu

期刊论文

Simultaneous enhanced ammonia and nitrate removal from secondary effluent in constructed wetlands using a new manganese-containing

期刊论文

Construction of defect-containing UiO-66/MoSe heterojunctions with superior photocatalytic performancefor wastewater treatment and mechanism insight

期刊论文

Stability analysis of alkaline nitrobenzene-containing wastewater by a catalyzed Fe-Cu treatment process

FAN Jinhong, XU Wenying, GAO Tingyao, MA Luming

期刊论文

Submerged arc plasma system combined with ozone oxidation for the treatment of wastewater containing

期刊论文

Multivalent manganese oxides with high electrocatalytic activity for oxygen reduction reaction

Xiangfeng Peng, Zhenhai Wang, Zhao Wang, Yunxiang Pan

期刊论文

Vanadium(IV) solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with

期刊论文

Broadening of appropriate demulsifier dosage range for latex-containing wastewater by sulfate addition

Shengzhi Zheng, Yudong Song, Yiming Li, Lidong Sun, Bin Hu, Mingdong An, Yuexi Zhou

期刊论文

Enhanced biohydrogen generation from organic wastewater containing N H 4 + by phototrophic bacteria Rhodobacter

Guanghong ZHENG, Zhuhui KANG, Yifan QIAN, Lei WANG,

期刊论文

Anaerobic treatment of wastewater containing methanol in up-flow anaerobic sludge bed (UASB) reactor

LIN Yishan, HE Yanling, MENG Zhuo, YANG Shucheng

期刊论文

Dendritic BiVO4 decorated with MnOx co-catalyst as an efficient hierarchical catalyst for photocatalytic ozonation

Jin Yang, Xuelian Liu, Hongbin Cao, Yanchun Shi, Yongbing Xie, Jiadong Xiao

期刊论文

A review on anammox process for the treatment of antibiotic-containing wastewater: Linking effects with

Jinjin Fu, Quan Zhang, Baocheng Huang, Niansi Fan, Rencun Jin

期刊论文

Linear viscoelastic behavior of asphalt binders and mixtures containing very high percentages of reclaimed

期刊论文

Lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery

期刊论文

高压高产含硫气井测试技术及应用

王世泽,唐瑞江, 赵祚培,杜林

期刊论文